Portland cement is the most commonly used type of cement in the construction industry, and its chemical reaction with water, known as hydration, is a complex process that generates heat. The heat of hydration refers to the heat released during the chemical reaction between cement and water, which is a crucial factor in the production of concrete. Understanding the heat of hydration and the resulting hydration products is essential for designing durable and efficient concrete structures.
Heat of Hydration
The heat of hydration of Portland cement is the heat released during the exothermic chemical reaction between cement and water. This reaction is highly exothermic and can generate significant amounts of heat, depending on the type and composition of the cement. During hydration, the water molecules react with the cement compounds to form calcium silicate hydrate (C-S-H) and calcium hydroxide (Ca(OH)2). The reaction can be expressed as follows:
C3S + 6H → C-S-H + Ca(OH)2 + 31.2 kcal/mol
C2S + 4.5H → C-S-H + Ca(OH)2 + 22.4 kcal/mol